When a certain conductance cell was filled with 0.1 M KCl, it has a resistance of 85 ohm at 25°C. When the same cell was filled with an aqueous solution of 0.052 M unknown electrolyte, the resistance was 96 ohms. Calculate the molar conductance of the electrolyte at this concentration.
[Specific conductance of 0.1 M KCl = 1.29 × 10⁻² ohm⁻¹ cm⁻¹]
[Specific conductance of 0.1 M KCl = 1.29 × 10⁻² ohm⁻¹ cm⁻¹]
Following reactions can occur at cathode during the electrolysis of aqueous silver nitrate solution using Pt electrodes:
(i) State the law which helps to determine the limiting molar conductivity of weak electrolyte.
(ii) Calculate limiting molar conductivity of CaSO₄ (limiting molar conductivity of calcium and sulphate ions are 119.0 and 160.0 Scm² mol⁻¹ respectively)
Looking at the setup of an electrochemical cell, what happens when \(E_{ext}\) > 1.1 V
The electrical resistance of a column of 0.05 M KOH solution of diameter 1 cm and length 45.5 cm is 4.55 × 10³ ohm. Calculate its molar conductivity.
The difference between the electrode potentials of two electrodes when no current is drawn through the cell is called ___________.
a. Cell potential.
b. Electromotive Force.
c. Potential difference.
d. Cell voltage.
The molar conductivity of 0.025 mol L⁻¹ methanoic acid is 46.1 S cm² mol⁻¹. Calculate its degree of dissociation and dissociation constant. Given λ°(H⁺) = 349.6 S cm² mol⁻¹ and λ°(HCOO⁻) = 54.6 S cm² mol⁻¹.
The conductivity of a 0.01 M solution of acetic acid at 298 K is 1.65 x 10⁻⁴ S cm⁻¹. Calculate molar conductivity () of the solution.
When a certain conductance cell was filled with 0.1 M KCl, it has a resistance of 85 ohm at 25°C. When the same cell was filled with an aqueous solution of 0.052 M unknown electrolyte, the resistance was 96 ohms. Calculate the molar conductance of the electrolyte at this concentration.
[Specific conductance of 0.1 M KCl = 1.29 × 10⁻² ohm⁻¹ cm⁻¹]
Complete the following reactions—
(i) Cr₂O₇²⁻ + 6Fe²⁺ + 14H⁺ →
(ii) 2CrO₄²⁻ + 2H⁺ →
(iii) 2MnO₄⁻ + 5C₂O₄²⁻ + 16H⁺ →
The electrical resistance of a column of 0.05 M KOH solution of diameter 1 cm and length 45.5 cm is 4.55 × 10³ ohm. Calculate its molar conductivity.
The magnetic moment of few transition metal ions
are given below:
Out of the following pairs, predict with reason which pair will allow greater conduction of electricity:
(i) Silver wire at 30°C or silver wire at 60°C.
(ii) 0.1 M \(CH_3\)COOH solution or 1 M \(CH_3\)COOH solution.
(iii) KCl solution at 20°C or KCl solution at 50°C.
(i) Account for the following :
(a) Cu⁺ is unstable in an aqueous solution.
(b) Transition metals form complex compounds.
(ii) Complete the following equation :
CrO₂₇²⁻ + 8H⁺ + 3NO₂⁻ →
Consider the standard electrode potential values (M²⁺/M) of the elements of the first transition series.