An antifreeze solution is prepared from 222.6 g of ethylene glycol \(C_2\)\(H_4\)\((OH)_2\) and 200 g of water. Calculate the molality of the solution. If the density of this solution be 1.072 \(gmL^{-1}\), what will be the molarity of the solution?
(a) 7.20 M
(b) 12.03 M
(c) 9.11 M
(d) 6 M
(a) 7.20 M
(b) 12.03 M
(c) 9.11 M
(d) 6 M
(d) 6 M
The partial pressure of ethane over a saturated solution containing 6.56 × 10⁻² g of ethane is 1 bar. If the solution were to contain 5.0 × 10⁻² g of ethane, then what will be the partial pressure of the gas ?
The osmotic pressure of a solution is directly proportional to
(a) the molecular concentration of the solute.
(b) the absolute temperature at a given concentration.
(c) the lowering of vapour pressure.
(d) all the above.
The molal elevation constant depends upon
(a) nature of solute.
(b) nature of the solvent.
(c) vapour pressure of the solution.
(d) enthalpy change.
Explain why on addition of 1 mol of NaCl to 1 litre of water, the boiling point of water increases, while addition of 1 mol of methyl alcohol to one litre of water decreases its boiling point.
State Raoult’s law for a solution containing nonvolatile solute. What type of deviation from Raoult’s law is shown by a solution of chloroform and acetone and why?
Which of the following aqueous solutions containing 10 g of solute in each case, has highest m.p.?
(a) NaCl solution
(b) KCl solution
(c) sugar solution
(d) glucose solution
(i) Write the colligative property which is used to find the molecular mass of macromolecules.
(ii) In non-ideal solution, what type of deviation shows the formation of minimum boiling azeotropes?
An alcohol X when treated with hot conc. \(H_2\)\(SO_4\) gave an alkene Y with formula \(C_4\)\(H_8\). This alkene on ozonolysis gives single product with molecular formula \(C_2\)\(H_4\)O. The alcohol is
(a) butan-1-ol.
(b) butan-2-ol.
(c) 2-methylpropan-1-ol.
(d) 2,2-dimethylbutynal-1-oI.
Which of the following is an example of vic-dihalide?
(a) Dichloromethane.
(b) 1,2-dichloroethane.
(c) Ethylidene chloride.
(d) Allyl chloride.
Order of esterification of alcohols are
(a) 3° > 1° > 2°.
(b) 2°> 3° > 1°.
(c) 1 ° > 2° > 3°.
(d) None of these.
The electronic configuration of Cu(II) is 3d⁹ whereas that of Cu(I) is 3d¹⁰. Which of the following is correct?
(a) Cu(II) is more stable
(b) Cu(II) is less stable
(c) Cu(I) and Cu(II) are equally stable
(d) Stability of Cu(I) and Cu(II) depends on nature of copper salts
An antifreeze solution is prepared from 222.6 g of ethylene glycol \(C_2\)\(H_4\)\((OH)_2\) and 200 g of water. Calculate the molality of the solution. If the density of this solution be 1.072 \(gmL^{-1}\), what will be the molarity of the solution?
(a) 7.20 M
(b) 12.03 M
(c) 9.11 M
(d) 6 M
Chlorine water on standing loses its yellow colour due to the formation of
a) Cl and HOCl.
b) HCl and HOCl.
c) HOCl and \(HOCl_2\).
d) HCl and \(HOCl_2\).