An alcohol X when treated with hot conc. \(H_2\)\(SO_4\) gave an alkene Y with formula \(C_4\)\(H_8\). This alkene on ozonolysis gives single product with molecular formula \(C_2\)\(H_4\)O. The alcohol is
(a) butan-1-ol.
(b) butan-2-ol.
(c) 2-methylpropan-1-ol.
(d) 2,2-dimethylbutynal-1-oI.
(a) butan-1-ol.
(b) butan-2-ol.
(c) 2-methylpropan-1-ol.
(d) 2,2-dimethylbutynal-1-oI.
(b) butan-2-ol.
Propanone on reaction with alkyl magnesium bromide followed by hydrolysis will produce
(a) primary alcohol
(b) secondary alcohol
(c) tertiary alcohol
(d) carboxylic acid
Which of the following alcohols gives 2-butenc on dehydration by conc.\(H_2\)\(SO_4\)?
(a) 2-methyl propene-2-ol.
(b) 2-methyl 1 -propanol.
(c) Butane-2-ol.
(d) Butane 1-ol.
One mole of ethyl acetate on treatment with an excess of \(LiAlH_4\) in dry ether and subsequent acidification produces
(a) 1 mole acetic acid + 1 mole ethyl alcohol.
(b) 1 mole ethyl alcohol + 1 mole methyl alcohol.
(c) 2 moles of ethyl alcohol.
(d) 1 mole of 2-butanol.
Which of the following alcohols will give the most stable carbocation during dehydration?
(a) 2-methyl-1-propanol.
(b) 2-methyl-2-propanol.
(c) 1-Butanol.
(d) 2-Butanol.
1-Phenylethanol can be prepared by the reaction of benzaldehyde with
(a) methyl bromide.
(b) ethyl iodide and magnesium.
(c) methyl iodide and magnesium.
(d) methyl bromide and aluminium bromide.
A compound X with the molecular formula \(C_2\)\(H_8\)O can be oxidised to another compound Y whose molecular formulae is \(C_3\)\(H_6\)\(O_2\). The compound X may be
(a) \(CH_3\)\(CH_2\)\(OCH_3\).
(b) \(CH_3\)\(CH_2\)CHO.
(c) \(CH_3\)\(CH_2\)\(CH_2\)OH.
(d) \(CH_3\)\(CHOHCH_3\).
What happens when tertiary butyl alcohol is passed over heated copper at 300°C?
(a) Secondary butyl alcohol is formed.
(b) 2-methylpropene is formed.
(c) 1-butene is formed.
(d) Butanol is formed.
Metallic radii of some transition elements are given below. Which of these elements will have highest density?
Which one is not correct statement?
a) Nitrogen does not form pentahalide due to non-availability of the d orbitals in its valence shell
b) Pentahalides are more covalent than trihalides.
c) In case of nitrogen, only \(NF_3\) is known to be stable
d) Trihalides except \(BiF_3\) are predominantly ionic in nature
Which of the following is not true about the ionic solids?
(A) Bigger ions form the close packed structure.
(B) Smaller ions occupy either the tetrahedral or the octahedral voids depending upon their size.
(C) Occupation of all the voids is not necessary.
(D) The fraction of octahedral or tetrahedral voids occupied depends upon the radii of the ions occupying the voids.
Which statement is incorrect about peptide bond?
(a) C-N bond length in proteins is longer than usual bond length of C-N bond.
(b) Spectroscopic analysis shows planar structure of -CO-NH- group
(c) C-N bond length in proteins is smaller than usual bond length of C-N bond
(d) None of the above
RNA and DNA are chiral molecules. Their chirality is due to :
(a) Chiral bases
(b) Chiral phosphate ester units
(c) D-sugar component
(d) L-sugar component.
Propanone on reaction with alkyl magnesium bromide followed by hydrolysis will produce
(a) primary alcohol
(b) secondary alcohol
(c) tertiary alcohol
(d) carboxylic acid
Which base is present in RNA but not in DNA?
(a) Uracil
(b) Cytosine
(c) Guanine
(d) Thymine