What would be the reactant and reagent used to obtain 2, 4-dimenthyl pentan-3-ol?
(a) Propanal and propyl magnesium bromide.
(b) 3-methylbutanal and 2-methyl magnesium iodide.
(c) 2-dimethylpropanone and methyl magnesium iodide.
(d) 2-methylpropanal and isopropyl magnesium iodide.
(a) Propanal and propyl magnesium bromide.
(b) 3-methylbutanal and 2-methyl magnesium iodide.
(c) 2-dimethylpropanone and methyl magnesium iodide.
(d) 2-methylpropanal and isopropyl magnesium iodide.
(d) 2-methylpropanal and isopropyl magnesium iodide.
1-Phenylethanol can be prepared by the reaction of benzaldehyde with
(a) methyl bromide.
(b) ethyl iodide and magnesium.
(c) methyl iodide and magnesium.
(d) methyl bromide and aluminium bromide.
What happens when tertiary butyl alcohol is passed over heated copper at 300°C?
(a) Secondary butyl alcohol is formed.
(b) 2-methylpropene is formed.
(c) 1-butene is formed.
(d) Butanol is formed.
Which of the following alcohols will give the most stable carbocation during dehydration?
(a) 2-methyl-1-propanol.
(b) 2-methyl-2-propanol.
(c) 1-Butanol.
(d) 2-Butanol.
Which of the following alcohols gives 2-butenc on dehydration by conc.\(H_2\)\(SO_4\)?
(a) 2-methyl propene-2-ol.
(b) 2-methyl 1 -propanol.
(c) Butane-2-ol.
(d) Butane 1-ol.
Propanone on reaction with alkyl magnesium bromide followed by hydrolysis will produce
(a) primary alcohol
(b) secondary alcohol
(c) tertiary alcohol
(d) carboxylic acid
Which of the following reagents cannot, be used to oxidise primary alcohols to aldehydes?
(a) \(CrO_3\) in anhydrous medium.
(b) \(KMnO_4\) in acidic medium.
(c) Pyridinium chlorochromate.
(d) Heat in the presence of Cu at 573 K.
One mole of ethyl acetate on treatment with an excess of \(LiAlH_4\) in dry ether and subsequent acidification produces
(a) 1 mole acetic acid + 1 mole ethyl alcohol.
(b) 1 mole ethyl alcohol + 1 mole methyl alcohol.
(c) 2 moles of ethyl alcohol.
(d) 1 mole of 2-butanol.
Which of the following is not true about the ionic solids?
(A) Bigger ions form the close packed structure.
(B) Smaller ions occupy either the tetrahedral or the octahedral voids depending upon their size.
(C) Occupation of all the voids is not necessary.
(D) The fraction of octahedral or tetrahedral voids occupied depends upon the radii of the ions occupying the voids.
Which is the most reactive towards SN1 reaction –
a) \(C_6\)\(H_5\)\(CH_2\)Cl.
b) \(C_6\)\(H_5\)CH(\(C_6\)\(H_5\))Br.
c) \(C_6\)\(H_5\)CH(\(CH_3\))Br.
d) \(C_6\)\(H_5\)C(\(CH_3\))(\(C_6\)\(H_5\))Br.
The order of reactivity of the following alcohols with halogen acids is
Which base is present in RNA but not in DNA?
(a) Uracil
(b) Cytosine
(c) Guanine
(d) Thymine
The reaction \({\\(CH_3\\)}_2\)CHCl + NaI → \({(\\CH_3\\)}_2\)CHI + NaCl is known as –
a) Finkelstein’s reaction.
b) Stephen’s reaction.
c) Kolbe’s reaction.
d) Wurtz reaction.
which is not the property of dioxygen gas
a) Dioxygen is a colourless and odourless gas.
b) Dioxygen is paramagnetic.
c) Dioxygen is diamagnetic.
d) Dioxygen is soluble in water which support aquatic life.
Which is the correct increasing order of boiling points of the following compounds?
1-Iodobutane, 1-Bromobutane, 1-Chlorobutane, Butane
(a) Butane < 1-Chlorobutane < 1-Bromobutane < 1-Iodobutane.
(b) 1-Iodobutane < 1-Bromobutane < 1-Chlorobutane < Butane.
(c) Butane < 1-Iodobutane < 1-Bromobutane < 1-Chlorobutane.
(d) Butane < 1-Chlorobutane < 1-Iodobutane < 1-Bromobutane.