Which is the most reactive towards SN1 reaction –
a) \(C_6\)\(H_5\)\(CH_2\)Cl.
b) \(C_6\)\(H_5\)CH(\(C_6\)\(H_5\))Br.
c) \(C_6\)\(H_5\)CH(\(CH_3\))Br.
d) \(C_6\)\(H_5\)C(\(CH_3\))(\(C_6\)\(H_5\))Br.
a) \(C_6\)\(H_5\)\(CH_2\)Cl.
b) \(C_6\)\(H_5\)CH(\(C_6\)\(H_5\))Br.
c) \(C_6\)\(H_5\)CH(\(CH_3\))Br.
d) \(C_6\)\(H_5\)C(\(CH_3\))(\(C_6\)\(H_5\))Br.
d) \(C_6\)\(H_5\)C(\(CH_3\))(\(C_6\)\(H_5\))Br.
Which of the following will have the maximum dipolemoment?
(a) \(CH_3\)F.
(b) \(CH_3\)Cl.
(c) \(CH_3\)Br.
(d) \(CH_3\)I.
Which of the following is an example of vic-dihalide?
(a) Dichloromethane.
(b) 1,2-dichloroethane.
(c) Ethylidene chloride.
(d) Allyl chloride.
A Grignard reagent may be made by reacting magnesium with
a) Methyl amine.
b) Diethyl ether.
c) Ethyl iodide.
d) Ethyl alcohol.
Write the structure of an isomer of compound C₄H₉Br which is most reactive towards reaction.
The Addition of HBr to 2—Pentene gives –
a) 2-Bromopentane only.
b) 3-Bromopentane only.
c) 2-Bromopentane and 3-Bromopentane.
d) 1-Bromopentane and 3-Bromopentane.
Benzene reacts with \(CH_3\)Cl in the presence of anhydrous \(AlCl_3\) to form:
(a) chlorobenzene
(b) benzylchloride
(c) xylene
(d) toluene
The reaction R-Br + NaCN → R – CN + NaBr is an example of –
(a) Elimination Reaction.
(b) Nucleophilic Substitution.
(c) Electrophilic Substitution.
(d) Oxidation Reduction.
An antifreeze solution is prepared from 222.6 g of ethylene glycol \(C_2\)\(H_4\)\((OH)_2\) and 200 g of water. Calculate the molality of the solution. If the density of this solution be 1.072 \(gmL^{-1}\), what will be the molarity of the solution?
(a) 7.20 M
(b) 12.03 M
(c) 9.11 M
(d) 6 M
The lowest boiling point of helium is due to its
a) Inertness
b) Gaseous nature
c) Weak van der Waals force between atoms
d) electronic configuration
The total number of tetrahedral voids in the face centred unit cell is _____.
(A) 6
(B) 8
(C) 10
(D) 12
Which of the following is an example of vic-dihalide?
(a) Dichloromethane.
(b) 1,2-dichloroethane.
(c) Ethylidene chloride.
(d) Allyl chloride.
The osmotic pressure of a solution is directly proportional to
(a) the molecular concentration of the solute.
(b) the absolute temperature at a given concentration.
(c) the lowering of vapour pressure.
(d) all the above.
Propanone on reaction with alkyl magnesium bromide followed by hydrolysis will produce
(a) primary alcohol
(b) secondary alcohol
(c) tertiary alcohol
(d) carboxylic acid
The letter ‘D’ in carbohydrates signifies-
(a) dextrorotatory
(b) configuration
(c) diamagnetic nature
(d) mode of synthesis