Which is the correct increasing order of boiling points of the following compounds?
1-Iodobutane, 1-Bromobutane, 1-Chlorobutane, Butane
(a) Butane < 1-Chlorobutane < 1-Bromobutane < 1-Iodobutane.
(b) 1-Iodobutane < 1-Bromobutane < 1-Chlorobutane < Butane.
(c) Butane < 1-Iodobutane < 1-Bromobutane < 1-Chlorobutane.
(d) Butane < 1-Chlorobutane < 1-Iodobutane < 1-Bromobutane.
1-Iodobutane, 1-Bromobutane, 1-Chlorobutane, Butane
(a) Butane < 1-Chlorobutane < 1-Bromobutane < 1-Iodobutane.
(b) 1-Iodobutane < 1-Bromobutane < 1-Chlorobutane < Butane.
(c) Butane < 1-Iodobutane < 1-Bromobutane < 1-Chlorobutane.
(d) Butane < 1-Chlorobutane < 1-Iodobutane < 1-Bromobutane.
(a) Butane < 1-Chlorobutane < 1-Bromobutane < 1-Iodobutane.
The Addition of HBr to 2—Pentene gives –
a) 2-Bromopentane only.
b) 3-Bromopentane only.
c) 2-Bromopentane and 3-Bromopentane.
d) 1-Bromopentane and 3-Bromopentane.
Molecules whose mirror image is non-superimposable over them are known as chiral. Which of the following molecules is chiral in nature?
(a) 2-Bromobutane.
(b)1-Bromobutane.
(c) 2-Bromopropane.
(d) 2-Bromopropan-2-ol.
Which of the following is an example of vic-dihalide?
(a) Dichloromethane.
(b) 1,2-dichloroethane.
(c) Ethylidene chloride.
(d) Allyl chloride.
When Benzene diazonium chloride is treated with cuprous chloride in HCl, Chlorobenzene is formed, This reaction is known as –
a) Etard Reaction
b) Perkin’s Reaction
c) Gattermann’s Reaction
d) Sand Meyer’s Reaction
The reaction R-Br + NaCN → R – CN + NaBr is an example of –
(a) Elimination Reaction.
(b) Nucleophilic Substitution.
(c) Electrophilic Substitution.
(d) Oxidation Reduction.
Aryl halides can not be prepared by the reaction of arylalcohols with \(PCl_3\), \(PCl_5\) or \(SOCl_2\) because :
(a) phenols are highly stable compounds.
(b) carbon-oxygen bond in phenols has a partial doublebond character.
(c) carbon-oxygen bond is highly polar
(d) all of these
Benzene reacts with \(CH_3\)Cl in the presence of anhydrous \(AlCl_3\) to form:
(a) chlorobenzene
(b) benzylchloride
(c) xylene
(d) toluene
The letter ‘D’ in carbohydrates signifies-
(a) dextrorotatory
(b) configuration
(c) diamagnetic nature
(d) mode of synthesis
A Grignard reagent may be made by reacting magnesium with
a) Methyl amine.
b) Diethyl ether.
c) Ethyl iodide.
d) Ethyl alcohol.
Interstitial compounds are formed when small atoms are dropped under the curved lattice of metals. Which of the following is not the characteristics property of interstitial compounds?
(A) They have high melting points in to pure metals
(B) They are very hard
(C) They retain metallic Conductivity
(D) They are chemically very reactive
The order of reactivity of the following alcohols with halogen acids is
Which of the following is incorrect for an ideal solution?
(a) \(∆H_{mix}\) =0
(b) \(∆V_{mix}\) = 0
(c) ∆P = \(P_{obs}\) – \(P_{calculated}\) = 0
(d) \(∆G_{mix}\) = 0
Which statement is incorrect about peptide bond?
(a) C-N bond length in proteins is longer than usual bond length of C-N bond.
(b) Spectroscopic analysis shows planar structure of -CO-NH- group
(c) C-N bond length in proteins is smaller than usual bond length of C-N bond
(d) None of the above
A compound is formed by two elements M and N. The element N forms ccp lattice and atoms of M occupy two atoms an Mercury 1/3rd of tetrahedral voids. What is the formula of the compound?
(A) \(MN_2\)
(B) \(M_2\)\(N_3\)
(C) \(M_3\)\(N_2\)
(D) \(M_2\)\(N_2\)