Which of the following alcohols will give the most stable carbocation during dehydration?
(a) 2-methyl-1-propanol.
(b) 2-methyl-2-propanol.
(c) 1-Butanol.
(d) 2-Butanol.
(a) 2-methyl-1-propanol.
(b) 2-methyl-2-propanol.
(c) 1-Butanol.
(d) 2-Butanol.
(b) 2-methyl-2-propanol.
Which of the following alcohols gives 2-butenc on dehydration by conc.H2SO4?
(a) 2-methyl propene-2-ol.
(b) 2-methyl 1 -propanol.
(c) Butane-2-ol.
(d) Butane 1-ol.
Order of esterification of alcohols are
(a) 3° > 1° > 2°.
(b) 2°> 3° > 1°.
(c) 1 ° > 2° > 3°.
(d) None of these.
What happens when tertiary butyl alcohol is passed over heated copper at 300°C?
(a) Secondary butyl alcohol is formed.
(b) 2-methylpropene is formed.
(c) 1-butene is formed.
(d) Butanol is formed.
Propanone on reaction with alkyl magnesium bromide followed by hydrolysis will produce
(a) primary alcohol
(b) secondary alcohol
(c) tertiary alcohol
(d) carboxylic acid
1-Phenylethanol can be prepared by the reaction of benzaldehyde with
(a) methyl bromide.
(b) ethyl iodide and magnesium.
(c) methyl iodide and magnesium.
(d) methyl bromide and aluminium bromide.
Which of the following is not true about the ionic solids?
(A) Bigger ions form the close packed structure.
(B) Smaller ions occupy either the tetrahedral or the octahedral voids depending upon their size.
(C) Occupation of all the voids is not necessary.
(D) The fraction of octahedral or tetrahedral voids occupied depends upon the radii of the ions occupying the voids.
Chlorine water on standing loses its yellow colour due to the formation of
a) Cl and HOCl.
b) HCl and HOCl.
c) HOCl and HOCl2.
d) HCl and HOCl2.
Which of the following is a network solid?
(A) SO2 (solid)
(B) I2
(C) Diamond
(D) H2O(ice)
A compound X with the molecular formula C2H8O can be oxidised to another compound Y whose molecular formulae is C3H6O2. The compound X may be
(a) CH3CH2OCH3.
(b) CH3CH2CHO.
(c) CH3CH2CH2OH.
(d) CH3CHOHCH3.
Which of the following conditions favours the existence of a substance in the solid state?
(A) High temperature
(B) Low temperature
(C) High thermal energy
(D) Weak cohesive forces
The decreasing order of boiling point of the following alcohols is
(a) 3-methylbuan-2-ol > 2-methylbutan-2-ol > pentan-1-ol.
(b) Pentan-1-ol > 3-methylbutan-2-ol > 2-methylbutan-2-ol.
(c) 2-methylbutan-2-ol > 3-methylbutan-2-ol > pentan-1-ol.
(d) 2-methylbutan-2-ol > pental-1-ol > 3-methylbutan-2-ol.
The letter ‘D’ in carbohydrates signifies-
(a) dextrorotatory
(b) configuration
(c) diamagnetic nature
(d) mode of synthesis