The decreasing order of boiling point of the following alcohols is
(a) 3-methylbuan-2-ol > 2-methylbutan-2-ol > pentan-1-ol.
(b) Pentan-1-ol > 3-methylbutan-2-ol > 2-methylbutan-2-ol.
(c) 2-methylbutan-2-ol > 3-methylbutan-2-ol > pentan-1-ol.
(d) 2-methylbutan-2-ol > pental-1-ol > 3-methylbutan-2-ol.
(a) 3-methylbuan-2-ol > 2-methylbutan-2-ol > pentan-1-ol.
(b) Pentan-1-ol > 3-methylbutan-2-ol > 2-methylbutan-2-ol.
(c) 2-methylbutan-2-ol > 3-methylbutan-2-ol > pentan-1-ol.
(d) 2-methylbutan-2-ol > pental-1-ol > 3-methylbutan-2-ol.
(b) Pentan-1-ol > 3-methylbutan-2-ol > 2-methylbutan-2-ol.
Which of the following alcohols gives 2-butenc on dehydration by conc.\(H_2\)\(SO_4\)?
(a) 2-methyl propene-2-ol.
(b) 2-methyl 1 -propanol.
(c) Butane-2-ol.
(d) Butane 1-ol.
Which of the following alcohols will give the most stable carbocation during dehydration?
(a) 2-methyl-1-propanol.
(b) 2-methyl-2-propanol.
(c) 1-Butanol.
(d) 2-Butanol.
What would be the reactant and reagent used to obtain 2, 4-dimenthyl pentan-3-ol?
(a) Propanal and propyl magnesium bromide.
(b) 3-methylbutanal and 2-methyl magnesium iodide.
(c) 2-dimethylpropanone and methyl magnesium iodide.
(d) 2-methylpropanal and isopropyl magnesium iodide.
1-Phenylethanol can be prepared by the reaction of benzaldehyde with
(a) methyl bromide.
(b) ethyl iodide and magnesium.
(c) methyl iodide and magnesium.
(d) methyl bromide and aluminium bromide.
What happens when tertiary butyl alcohol is passed over heated copper at 300°C?
(a) Secondary butyl alcohol is formed.
(b) 2-methylpropene is formed.
(c) 1-butene is formed.
(d) Butanol is formed.
One mole of ethyl acetate on treatment with an excess of \(LiAlH_4\) in dry ether and subsequent acidification produces
(a) 1 mole acetic acid + 1 mole ethyl alcohol.
(b) 1 mole ethyl alcohol + 1 mole methyl alcohol.
(c) 2 moles of ethyl alcohol.
(d) 1 mole of 2-butanol.
An alcohol X when treated with hot conc. \(H_2\)\(SO_4\) gave an alkene Y with formula \(C_4\)\(H_8\). This alkene on ozonolysis gives single product with molecular formula \(C_2\)\(H_4\)O. The alcohol is
(a) butan-1-ol.
(b) butan-2-ol.
(c) 2-methylpropan-1-ol.
(d) 2,2-dimethylbutynal-1-oI.
The electronic configuration of Cu(II) is 3d⁹ whereas that of Cu(I) is 3d¹⁰. Which of the following is correct?
(a) Cu(II) is more stable
(b) Cu(II) is less stable
(c) Cu(I) and Cu(II) are equally stable
(d) Stability of Cu(I) and Cu(II) depends on nature of copper salts
The sharp melting point of crystalline solids is due to ___________.
(A) a regular arrangement of constituent particles observed over a short distance in the crystal lattice.
(B) a regular arrangement of constituent particles observed over a long distance in the crystal lattice.
(C) same arrangement of constituent particles in different directions.
(D) different arrangements of constituent particles in different directions.
Which of the following statement is false?
a) Radon is obtained from the decay of radium
b) Helium is an inert gas
c) Xenon is the most reactive among the rare gases
d) The most abundant rare gas found in the atmosphere is helium
When KMnO₄ solution is added to oxalic acid solution, the decolourisation is slow in the beginning but becomes instantaneous after some time because
(a) CO₂ is formed as the product.
(b) The reaction is exothermic.
(c) MnO₄⁻ catalyses the reaction.
(d) Mn²⁺ acts as an auto-catalyst.
When Benzene diazonium chloride is treated with cuprous chloride in HCl, Chlorobenzene is formed, This reaction is known as –
a) Etard Reaction
b) Perkin’s Reaction
c) Gattermann’s Reaction
d) Sand Meyer’s Reaction
Molecules whose mirror image is non-superimposable over them are known as chiral. Which of the following molecules is chiral in nature?
(a) 2-Bromobutane.
(b)1-Bromobutane.
(c) 2-Bromopropane.
(d) 2-Bromopropan-2-ol.
Which of the following reagents cannot, be used to oxidise primary alcohols to aldehydes?
(a) \(CrO_3\) in anhydrous medium.
(b) \(KMnO_4\) in acidic medium.
(c) Pyridinium chlorochromate.
(d) Heat in the presence of Cu at 573 K.