Chlorobenzene is formed by reaction of chlorine with benzene in the presence of \(AlCl_3\). Which of the following species attacks the benzene ring in this reaction?
(a) \(Cl^+\)
(b) \(Cl^-\)
(c) \(AlCl_3\)
(d) \({[\\(AlCl_4\\)]}^-\)
(a) \(Cl^+\)
(b) \(Cl^-\)
(c) \(AlCl_3\)
(d) \({[\\(AlCl_4\\)]}^-\)
(a) \(Cl^+\)
Which of the following will have the maximum dipolemoment?
(a) \(CH_3\)F.
(b) \(CH_3\)Cl.
(c) \(CH_3\)Br.
(d) \(CH_3\)I.
Benzene reacts with \(CH_3\)Cl in the presence of anhydrous \(AlCl_3\) to form:
(a) chlorobenzene
(b) benzylchloride
(c) xylene
(d) toluene
Molecules whose mirror image is non-superimposable over them are known as chiral. Which of the following molecules is chiral in nature?
(a) 2-Bromobutane.
(b)1-Bromobutane.
(c) 2-Bromopropane.
(d) 2-Bromopropan-2-ol.
The reaction R-Br + NaCN → R – CN + NaBr is an example of –
(a) Elimination Reaction.
(b) Nucleophilic Substitution.
(c) Electrophilic Substitution.
(d) Oxidation Reduction.
When Benzene diazonium chloride is treated with cuprous chloride in HCl, Chlorobenzene is formed, This reaction is known as –
a) Etard Reaction
b) Perkin’s Reaction
c) Gattermann’s Reaction
d) Sand Meyer’s Reaction
Which is the most reactive towards SN1 reaction –
a) \(C_6\)\(H_5\)\(CH_2\)Cl.
b) \(C_6\)\(H_5\)CH(\(C_6\)\(H_5\))Br.
c) \(C_6\)\(H_5\)CH(\(CH_3\))Br.
d) \(C_6\)\(H_5\)C(\(CH_3\))(\(C_6\)\(H_5\))Br.
The reaction \({\\(CH_3\\)}_2\)CHCl + NaI → \({(\\CH_3\\)}_2\)CHI + NaCl is known as –
a) Finkelstein’s reaction.
b) Stephen’s reaction.
c) Kolbe’s reaction.
d) Wurtz reaction.
The lowest boiling point of helium is due to its
a) Inertness
b) Gaseous nature
c) Weak van der Waals force between atoms
d) electronic configuration
What would be the reactant and reagent used to obtain 2, 4-dimenthyl pentan-3-ol?
(a) Propanal and propyl magnesium bromide.
(b) 3-methylbutanal and 2-methyl magnesium iodide.
(c) 2-dimethylpropanone and methyl magnesium iodide.
(d) 2-methylpropanal and isopropyl magnesium iodide.
Which of the following is a network solid?
(A) (solid)
(B)
(C) Diamond
(D) (ice)
There is a considerable increase in covalent radius from N to P. However, from As to Bi only a small increase in covalent radius is observed. This is due to
a) Increase in number of shells
b) increase in valence electrons
c) increase in ionisation enthalpy
d) the presence of completely filled d and/or f orbitals
Which of the following alcohols gives 2-butenc on dehydration by conc.\(H_2\)\(SO_4\)?
(a) 2-methyl propene-2-ol.
(b) 2-methyl 1 -propanol.
(c) Butane-2-ol.
(d) Butane 1-ol.
Acid catalysed dehydration of t-butanol is faster than that of n-butanol because
(a) tertiary carbocation is more stable than primary carbocation.
(b) primary carbocation is more stable than tertiary carbocation.
(c) t-butanol has a higher boiling point.
(d) rearrangement takes place during dehydration of t- butanol.
The difference between the electrode potentials of two electrodes when no current is drawn through the cell is called ___________.
a. Cell potential.
b. Electromotive Force.
c. Potential difference.
d. Cell voltage.