Molecules whose mirror image is non-superimposable over them are known as chiral. Which of the following molecules is chiral in nature?
(a) 2-Bromobutane.
(b)1-Bromobutane.
(c) 2-Bromopropane.
(d) 2-Bromopropan-2-ol.
(a) 2-Bromobutane.
(b)1-Bromobutane.
(c) 2-Bromopropane.
(d) 2-Bromopropan-2-ol.
(a) 2-Bromobutane.
The Addition of HBr to 2—Pentene gives –
a) 2-Bromopentane only.
b) 3-Bromopentane only.
c) 2-Bromopentane and 3-Bromopentane.
d) 1-Bromopentane and 3-Bromopentane.
Which of the following is an example of vic-dihalide?
(a) Dichloromethane.
(b) 1,2-dichloroethane.
(c) Ethylidene chloride.
(d) Allyl chloride.
Benzene reacts with \(CH_3\)Cl in the presence of anhydrous \(AlCl_3\) to form:
(a) chlorobenzene
(b) benzylchloride
(c) xylene
(d) toluene
A Grignard reagent may be made by reacting magnesium with
a) Methyl amine.
b) Diethyl ether.
c) Ethyl iodide.
d) Ethyl alcohol.
Which of the following will have the maximum dipolemoment?
(a) \(CH_3\)F.
(b) \(CH_3\)Cl.
(c) \(CH_3\)Br.
(d) \(CH_3\)I.
Chlorobenzene is formed by reaction of chlorine with benzene in the presence of \(AlCl_3\). Which of the following species attacks the benzene ring in this reaction?
(a) \(Cl^+\)
(b) \(Cl^-\)
(c) \(AlCl_3\)
(d) \({[\\(AlCl_4\\)]}^-\)
Electronic configuration of a transition element X in +3 oxidation state is [Ar]3d⁵. What is its atomic number?
(a) 25
(b) 26
(c) 27
(d) 24
The osmotic pressure of a solution is directly proportional to
(a) the molecular concentration of the solute.
(b) the absolute temperature at a given concentration.
(c) the lowering of vapour pressure.
(d) all the above.
Although Zirconium belongs to 4d transition series and Hafnium to 5d transition series even then they show similar physical and chemical properties because
(a) both belong to d-block.
(b) both have same number of electrons.
(c) both have similar atomic radius.
(d) both belong to the same group of the periodic table.
The total number of tetrahedral voids in the face centred unit cell is _____.
(A) 6
(B) 8
(C) 10
(D) 12
Which is the correct statement?
a) valence shell electronic configuration of group 16 elements is \(ns^1\)\(np^4\).
b) the elements of group 16 have lower ionisation enthalpy values compared to those of Group 15 in the corresponding periods.
c) Oxygen atom has more negative electron gain enthalpy than sulphur.
d) oxygen has the highest electronegativity value amongst the elements.
The lowest boiling point of helium is due to its
a) Inertness
b) Gaseous nature
c) Weak van der Waals force between atoms
d) electronic configuration
Acid catalysed dehydration of t-butanol is faster than that of n-butanol because
(a) tertiary carbocation is more stable than primary carbocation.
(b) primary carbocation is more stable than tertiary carbocation.
(c) t-butanol has a higher boiling point.
(d) rearrangement takes place during dehydration of t- butanol.