An unknown alcohol is treated with “Lucas reagent” to determine whether the alcohol is primary, secondary or tertiary. Which alcohol reacts fastest and by what mechanism?
(a) Tertiary alcohol by SN2.
(b) Secondary alcohol by SN1.
(c) Tertiary alcohol by SN1.
(d) Secondary alcohol by SN2.
(a) Tertiary alcohol by SN2.
(b) Secondary alcohol by SN1.
(c) Tertiary alcohol by SN1.
(d) Secondary alcohol by SN2.
(c) Tertiary alcohol by SN1.
Propanone on reaction with alkyl magnesium bromide followed by hydrolysis will produce
(a) primary alcohol
(b) secondary alcohol
(c) tertiary alcohol
(d) carboxylic acid
What happens when tertiary butyl alcohol is passed over heated copper at 300°C?
(a) Secondary butyl alcohol is formed.
(b) 2-methylpropene is formed.
(c) 1-butene is formed.
(d) Butanol is formed.
One mole of ethyl acetate on treatment with an excess of \(LiAlH_4\) in dry ether and subsequent acidification produces
(a) 1 mole acetic acid + 1 mole ethyl alcohol.
(b) 1 mole ethyl alcohol + 1 mole methyl alcohol.
(c) 2 moles of ethyl alcohol.
(d) 1 mole of 2-butanol.
1-Phenylethanol can be prepared by the reaction of benzaldehyde with
(a) methyl bromide.
(b) ethyl iodide and magnesium.
(c) methyl iodide and magnesium.
(d) methyl bromide and aluminium bromide.
Which of the following alcohols will give the most stable carbocation during dehydration?
(a) 2-methyl-1-propanol.
(b) 2-methyl-2-propanol.
(c) 1-Butanol.
(d) 2-Butanol.
Which of the following reagents cannot, be used to oxidise primary alcohols to aldehydes?
(a) \(CrO_3\) in anhydrous medium.
(b) \(KMnO_4\) in acidic medium.
(c) Pyridinium chlorochromate.
(d) Heat in the presence of Cu at 573 K.
Which of the following alcohols gives 2-butenc on dehydration by conc.\(H_2\)\(SO_4\)?
(a) 2-methyl propene-2-ol.
(b) 2-methyl 1 -propanol.
(c) Butane-2-ol.
(d) Butane 1-ol.
A compound is formed by two elements M and N. The element N forms ccp lattice and atoms of M occupy two atoms an Mercury 1/3rd of tetrahedral voids. What is the formula of the compound?
(A) \(MN_2\)
(B) \(M_2\)\(N_3\)
(C) \(M_3\)\(N_2\)
(D) \(M_2\)\(N_2\)
Which is incorrect statement.
a) Oxygen is the most abundant of all the elements on earth
b) Organic materials such as eggs, proteins, garlic, onion, mustard, hair and wool contain sulphur
c) Selenium and tellurium are found as metal selenides and tellurides in sulphide ores
d) Livermorium is a natural radioactive element
The order of reactivity of the following alcohols with halogen acids is
Chlorine water on standing loses its yellow colour due to the formation of
a) Cl and HOCl.
b) HCl and HOCl.
c) HOCl and \(HOCl_2\).
d) HCl and \(HOCl_2\).
The lattice site in a pure crystal cannot be occupied by __________.
(A) Molecule
(B) Ion
(C) Electron
(D) Atom
Which base is present in RNA but not in DNA?
(a) Uracil
(b) Cytosine
(c) Guanine
(d) Thymine
The decreasing order of boiling point of the following alcohols is
(a) 3-methylbuan-2-ol > 2-methylbutan-2-ol > pentan-1-ol.
(b) Pentan-1-ol > 3-methylbutan-2-ol > 2-methylbutan-2-ol.
(c) 2-methylbutan-2-ol > 3-methylbutan-2-ol > pentan-1-ol.
(d) 2-methylbutan-2-ol > pental-1-ol > 3-methylbutan-2-ol.