The potential of a hydrogen electrode at pH = 10 is
a. 0.591 V
b. 0.00 V
c. – 0.591 V
d. -0.059 V
a. 0.591 V
b. 0.00 V
c. – 0.591 V
d. -0.059 V
c. – 0.591 V.
The conductivity of 0.20 M solution of KCl at 298 K is 0.025 Scm⁻¹. Calculate its molar conductivity.
The conductivity of metals decreases while that of electrolytes increases with increase in temperature. Why?
Calculate pH of following half-cell. Pt, \(H_2\) / \(H_2\)\(SO_4\) , if its electrode potential is 0.03V.
State Kohlrausch law of independent migration of ions. Why does the conductivity of a solution decrease with dilution ?
Calculate emf of the following cell
Cd/\(Cd^{2+}\) (.10 M)//\(H_+\) (.20 M)/\(H_2\) (0.5 atm)/Pt
[Given E° for \(Cd^{2+}\) /Cd = -0.403V]
In the periodic table of the elements, the phrase “middle row anomaly” refers to
a) Middle elements of periodic table are transition metals.
b) Middle element of each group is unstable.
c) the relative instability of bromine oxides compared to the other halogen oxides.
d) The higher oxides of halogens tend to be more stable than the lower ones.
Aryl halides can not be prepared by the reaction of arylalcohols with \(PCl_3\), \(PCl_5\) or \(SOCl_2\) because :
(a) phenols are highly stable compounds.
(b) carbon-oxygen bond in phenols has a partial doublebond character.
(c) carbon-oxygen bond is highly polar
(d) all of these
Limiting molar conductivity of NH4OH is equal to -:
a. Λᵒₘ(NH₄Cl) + Λᵒₘ(NaCl) + Λᵒₘ(NaOH)
b. Λᵒₘ(NaOH) + Λᵒₘ(NaCl) - Λᵒₘ(NH₄Cl)
c. Λᵒₘ(NaOH) - Λᵒₘ(NH₄Cl) - Λᵒₘ(HCl)
d. Λᵒₘ(NH₄Cl) + Λᵒₘ(NaOH) - Λᵒₘ(NaCl)
Equimolar solutions in the same solvent have-
(a) Same boiling point but different freezing point
(b) Same freezing point, but different boiling point
(c) Same boiling and same freezing point
(d) Different boiling and different freezing points
How is electrical conductance of a conductor related with length and area of cross-section of the conductor?
a. G = \(l. a.k^{-1}\)
b. G = \(k. l.a^{-1}\)
c. G = \(k.a. l^{-1}\)
d. G = \(k. l.a^{-2}\)
The reaction R-Br + NaCN → R – CN + NaBr is an example of –
(a) Elimination Reaction.
(b) Nucleophilic Substitution.
(c) Electrophilic Substitution.
(d) Oxidation Reduction.
Chlorobenzene is formed by reaction of chlorine with benzene in the presence of \(AlCl_3\). Which of the following species attacks the benzene ring in this reaction?
(a) \(Cl^+\)
(b) \(Cl^-\)
(c) \(AlCl_3\)
(d) \({[\\(AlCl_4\\)]}^-\)