Assertion: Isotonic solutions do not show any osmosis when placed side by side.
Reason: Isotonic solutions have same solute concentration.
A. If both Assertion and Reason are correct and reason is the correct explanation of Assertion .
B. If both Assertion and Reason are correct and reason is not correct explanation of Assertion
C. If Assertion is correct but Reason is incorrect.
D. If Assertion is incorrect and Reason is correct.
Reason: Isotonic solutions have same solute concentration.
A. If both Assertion and Reason are correct and reason is the correct explanation of Assertion .
B. If both Assertion and Reason are correct and reason is not correct explanation of Assertion
C. If Assertion is correct but Reason is incorrect.
D. If Assertion is incorrect and Reason is correct.
C. If Assertion is correct but Reason is incorrect.
Assertion: Molarity of the solution changes with temperature.
Reason: Molarity is a colligative property.
A. If both Assertion and Reason are correct and reason is the correct explanation of Assertion .
B. If both Assertion and Reason are correct and reason is not correct explanation of Assertion
C. If Assertion is correct but Reason is incorrect.
D. If Assertion is incorrect and Reason is correct.
Assertion: Cooking time is reduced in pressure cooker.
Reason: Boiling point of water inside the pressure cooker is lowered.
A. If both Assertion and Reason are correct and reason is the correct explanation of Assertion .
B. If both Assertion and Reason are correct and reason is not correct explanation of Assertion
C. If Assertion is correct but Reason is incorrect.
D. If Assertion is incorrect and Reason is correct.
Assertion: An aqueous solution of NaCl freezes below 273 K.
Reason: Vapour pressure of the solution is less than that of the pure solvent.
A. If both Assertion and Reason are correct and reason is the correct explanation of Assertion .
B. If both Assertion and Reason are correct and reason is not correct explanation of Assertion
C. If Assertion is correct but Reason is incorrect.
D. If Assertion is incorrect and Reason is correct.
Assertion: 1 M glucose will have a higher boiling point than 2 M glucose.
Reason: Elevation in boiling point is a colligative property which depends upon the number of particles of solute in the solution.
A. If both Assertion and Reason are correct and reason is the correct explanation of Assertion .
B. If both Assertion and Reason are correct and reason is not correct explanation of Assertion
C. If Assertion is correct but Reason is incorrect.
D. If Assertion is incorrect and Reason is correct.
(i) Gas (A) is more soluble in water than Gas (B) at the same temperature. Which one of the two gases will have the higher value of KH (Henry’s constant) and why ?
(ii) In non-ideal solution, what type of deviation shows the formation of maximum boiling azeotropes ?
The osmotic pressure of a solution is directly proportional to
(a) the molecular concentration of the solute.
(b) the absolute temperature at a given concentration.
(c) the lowering of vapour pressure.
(d) all the above.
Equimolar solutions in the same solvent have-
(a) Same boiling point but different freezing point
(b) Same freezing point, but different boiling point
(c) Same boiling and same freezing point
(d) Different boiling and different freezing points
Assertion: The packing efficiency is maximum for the fcc structure.
Reason: The coordination number is 12 in fcc structures.
[A] – Assertion & reason both statements are correct and reason is the correct explanation of assertion.
[B] – Assertion & reason both are the correct statements but reason is not the correct explanation of the assertion.
[C] – Assertion is correct statement and reason is incorrect statement.
[D] – Assertion is incorrect statement and reason is correct statement
Assertion: IUPAC name of the compound is 2-Ethoxy-2-methylethane.
Reason: In IUPAC nomenclature, ether is regarded as hydrocarbon derivative in which a hydrogen atom is replaced by -OR or -OAr group [where R = alkyl group and Ar = aryl group]
(a) Both assertion and reason are true and the reason is the correct explanation of assertion.
(b) Both assertion and reason are true but the reason is not the correct explanation of assertion.
(c) Assertion is true but reason is false.
(d) Assertion is false but reason is true.
Read the passage given below and answer the following questions:
The polarity of carbon-halogen bond of alkyl halides is responsible for their Nucleophilic substitution, elimination and their reaction with metal atoms to form organ metallic compounds. Nucleophilic substitution reactions are categorized into SN1 and SN2 on the basis of their kinetic properties. Chirality has a profound role in understanding the reaction mechanisms of SN1 and SN2 reactions. SN2 reactions of chiral alkyl halides are characterized by the inversion of configuration while SN1 reactions are characterized by racemisation.
ASSERTION -REASON TYPE
A statement of assertion is followed by a statement of reason. Mark the correct choice from the options given below:
(a) Both assertion and reason are true and reason is the correct explanation of assertion.
(b) Both assertion and reason are true but reason is not the correct explanation of assertion.
(c) Assertion is true but reason is false.
(d) Assertion is false but reason is true.
(i) Assertion : SN2 reactions do not proceed with retention of configuration.
Reason : SN2 reactions proceed in a single step.
(ii) Assertion : Tertiary alkyl halides show high reactivity in SN1 reaction.
Reason : Tertiary carbocation has more stability.
(iii) Assertion : Nucleophilic substitution reaction in an optically active alkyl halide gives a mixture of enantiomers.
Reason : Reaction occurs by SN1 mechanism.
(iv) Assertion : Primary allylic halides show higher reactivity in SN1 reactions than other primary alkyl halides.
Reason : Intermediate carbocation is stabilized by resonance.
Assertion :- O3 acts as a powerful oxidising agent.
Reason :- O3 oxidises lead sulphide to lead sulphate & iodide ions to iodine
a) Assertion and reason both are correct statements and reason is correct explanation for assertion.
b) Assertion and reason both are correct statements but reason is not correct explanation for assertion.
c) Assertion is correct statement but reason is wrong statement.
d) Assertion is wrong statement but reason is correct statement.
Assertion: Addition reaction of water to but-1-ene in acidic medium yields butan-2-ol.
Reason: Addition of water in acidic medium proceeds through the formation of primary carbocation.
(a) Both assertion and reason are true and the reason is the correct explanation of assertion.
(b) Both assertion and reason are true but the reason is not the correct explanation of assertion.
(c) Assertion is true but reason is false.
(d) Assertion is false but reason is true.
Assertion: Like bromination of benzene, bromination of phenol is also carried out in the presence of Lewis acid.
Reason: Lewis acid polarises the bromine molecule.
(a) Both assertion and reason are true and the reason is the correct explanation of assertion.
(b) Both assertion and reason are true but the reason is not the correct explanation of assertion.
(c) Assertion is true but reason is false.
(d) Assertion is false but reason is true.
Assertion: Diamond and graphite do not have the same crystal structure.
Reason: Diamond is crystalline while graphite is amorphous.
[A] – Assertion & reason both statements are correct and reason is the correct explanation of assertion.
[B] – Assertion & reason both are the correct statements but reason is not the correct explanation of the assertion.
[C] – Assertion is correct statement and reason is incorrect statement.
[D] – Assertion is incorrect statement and reason is correct statement